Hydraulics 101
Smller hole in the tip makes more pressure, larger hole makes less pressure if everything else is constant (pump displacment)
Flow sensitive unloaders or pressure sensitive unloaders are both attached to apump, the pump will only move X amount of water (all thing being constant), reduce the size of the tip and the pressure increases, enlarge the tip and the pressure decreases, the flow amount obviously increases with the increase in size of the tip size.
The 'flow charts' are based on the amount of water that will flow throigh a fixed orifice at a given pressure. They do not take in account pressure drop due to hose, temperature etc. Basicly they charts are a guide, they are pretty accurate, but still a guide.
My experience is typical soap injecters (downstream) start flowing soap with a '20 tip size on a 3000 or 3500 psi unloader machine that flows around 5 gpm, which means the soap injecter starts sucking soap around 250 psi, and would also suck soap with a '40 tip but the pressure would be around 70 psi. As the tip size increases the pressure drops if the flow remains the same.
Good Luck